Offers complete coverage of: Carbide, Alkylidyne, Alkylidene, Alkyl, and Alkane Derivatives; Noncyclic Carbon-Clusters and Unsaturated Hydrocarbon Derivatives; and Cyclic, Unsaturated Organometallic Derivatives.
A comprehensive compilation of the available experimental and theoretical vibrational data for organometallic compounds and its role in evaluating the structures, bonding, and properties of these key compounds This unique book offers a thorough review of the literature dealing with vibrational data obtained using various phases, including matrices, reported for organometallic compounds from infrared spectra, Raman spectra, and several other techniques. It is the only one that compiles the available experimental and theoretical vibrational data on these compounds, and which discusses the importance of this information and its role in evaluating structures, bonding, and other important properties. It also treats the use of DFT and other theoretical calculations to analyze the vibrational data and to predict properties associated with these compounds. The book also includes vibrational data for organic species that form on metal and other surfaces. Vibrational Spectra of Organometallics: Theoretical and Experimental Data offers complete coverage of: Carbide, Alkylidyne, Alkylidene, Alkyl, and Alkane Derivatives; Noncyclic Carbon Clusters and Unsaturated Hydrocarbon Derivatives; and Cyclic, Unsaturated Organometallic Derivatives. By summarizing work that has already been done on organometallic compounds, it serves as an important reference for those studying their vibrational spectra and will, in the end, lead to a clearer understanding of other research that needs to be done in order to help researchers determine new research directions. An important reference for those studying the vibrational spectra of organometallic compounds Gathers the existing experimental and theoretical vibrational data and discusses its significance in assessing structures, bonding, and other principle properties Includes DFT methods for the interpretation of spectra, which has been one of the major developments of the last two decades Vibrational Spectra of Organometallics: Theoretical and Experimental Data is an important reference for researchers and practitioners in the areas of inorganic, organometallic, organic, and surface chemistry who have an interest in using vibrational data to characterize the bonding, composition, reactions, and structures of organometallic compounds, and organic species that are formed on various surfaces.
Table of Contents
Preface xi Part I Carbide, Alkylidyne, Alkylidene, Alkyl, and Alkane Compounds 1 1 Monocarbide Complexes 3 2 Terminal and Bridging Methylidyne (CH) and Other Alkylidyne Complexes 9 3 Terminal and Bridging Methylidene (CH2) and Other Alkylidene Complexes 13 4 Methyl Complexes 21 4.1 Neutral Monomeric Complexes 21 4.2 Cationic and Anionic Monomeric Complexes 29 4.3 Bridged Methyl Complexes 33 5 Methane and Other Alkane Complexes 37 6 Terminal and Bridged Ethyl Complexes 43 7 Propyl, Butyl, and Pentyl Complexes 49 8 Cycloalkyl and Cycloalkane Complexes 53 9 Saturated Heterometallacycle Complexes 55 10 Benzyl Complexes 59 11 Mixed Alkyl and Alkyl-Aryl Complexes 61 12 Surface Bound Alkyl, Alkane, and Alkyl-Metal Complexes 63 12.1 Metal Surfaces 63 12.2 Metalloid Surfaces 65 12.3 Inorganic Oxide Surfaces 66 13 Alkyl, Alkylidyne, and Alkylidene Complexes with Other Functional Groups 69 13.1 Hydrides 69 13.2 Halides and Mixed Halides and Hydrides 84 13.3 Pseudohalides 120 13.4 Carbonyl and Dinitrogen Complexes 135 13.5 Diazomethane (CH2N+=N ) and Related Complexes 139 13.6 Organic Isocyanides (Isonitriles, R?N C), Organic Nitriles (R?C N) and Iminoacyl Complexes 139 13.7 Carbon Dioxide and Carbon Disulfide Complexes 141 13.8 Aqua, Hydroxide, Oxide, Peroxide, and Oxyhalide Complexes 146 13.9 Hydrogen Sulfide, Mercaptide, Sulfide, and Disulfide Complexes 161 13.10 Alkoxide, Organoperoxide, Ether, and Alcohol Complexes 164 13.11 Alkylsulfide, Dialkylsulfide, and Methanethiol Complexes 171 13.12 Carboxylate, Thiocarboxylate, Dithiocarboxylate, and Xanthate Complexes 173 13.13 Formaldehyde, Formyl, Acetaldehyde, Acyl, and Related Complexes 180 13.14 Ketone, Ketenyl, and Related Complexes 187 13.15 ?Diketonate and Related Complexes 190 13.16 Nitrogen Bases and Miscellaneous Lewis?Base and Chelating Ligands 195 14 Complexes with Metal-Metal Bonds 215 14.1 Homonuclear Bonds 215 14.2 Heteronuclear Bonds 219 15 Halogenated Alkyl Complexes 225 15.1 Main Group Elements 225 15.2 Transition and Actinide Elements 234 Part I References 241 Part II Noncyclic Carbon-Clusters and Unsaturated Hydrocarbon Compounds 299 16 Linear Carbon Cluster Complexes 301 16.1 C2 Complexes 301 16.2 C3 Complexes 304 16.3 C4 Complexes 304 16.4 C5 and Larger Complexes 305 17 Ethynyl, Ethyne, and Related Complexes 309 17.1 Main Group Elements 309 17.2 d and f Block Elements 319 18 Vinyl and Vinylidene Complexes 343 19 Ethene and Related Monoalkene Complexes 355 20 Allyl and Related Complexes 371 21 Allene and Related Complexes 387 22 Conjugated and Nonconjugated Diolefin and Related Complexes 391 22.1 Butadiene and Butatriene Complexes 391 22.2 Pentadiene Complexes 396 22.3 Hexadiene Complexes 398 22.4 Miscellaneous Olefin Complexes 399 Part II References 403 Part III Cyclic, Unsaturated Organometallic Compounds 427 23 Metal Complexes of Fullerenes and Other Nonlinear Carbon Clusters 429 24 Three?carbon Rings 433 25 Four?carbon Rings 435 26 Five?carbon Rings 441 26.1 Cyclopentene and Cyclopentyl Complexes 441 26.2 1,3?Cyclopentadiene, Cyclopentadienone, and Related Complexes 441 26.3 Anionic Cyclopentadienide Complexes 443 26.4 Covalent Cyclopentadienyl Complexes 446 27 Six?carbon Rings 547 27.1 Cyclohexene Complexes 547 27.2 Cyclohexadiene, Cyclohexadienyl, Oxocyclohexadienyl, and Quinone Complexes 547 27.3 Neutral, Cationic, and Anionic Phenyl Complexes 550 27.4 Phenyl Compounds with Other Functional Groups 559 27.5 Phenyl Complexes with Metal-Metal Bonds 585 27.6 Ring?Substituted Phenyl Complexes 588 27.7 Perhalogenated Phenyl Complexes 591 27.8 Benzene Ring Complexes 596 27.9 Ring?Substituted Benzene Complexes 608 27.10 Benzyne Complexes 611 28 Seven?carbon Rings 613 29 Eight?carbon Rings 615 30 Nine?carbon Rings 629 31 Ten?carbon Rings 631 32 Coupled Organic Ring Complexes 633 33 Fused Organic Ring Complexes 635 33.1 Pentalenyl Complexes 635 33.2 Indene and Indenyl Complexes 635 33.3 Fluorene and Fluorenyl Complexes 641 33.4 Indacenyl Complexes 641 33.5 Azulene Complexes 641 33.6 Naphthalene and Larger Fused Aromatic Ring Complexes 642 34 Miscellaneous Cyclic Olefin and Mixed Ring Complexes 643 35 Carboranes and Metallacarboranes 647 36 Five? and Six?membered Heterocyclic Rings and Their Metal Complexes 651 37 Unsaturated Metallacycle Rings with Four or More Atoms 657 Part III References 661 Index 709